Labels and plant-backs - what you need to know for 2018
Author: Richard Holzknecht, Grains Research and Development Corporation | Date: 13 Feb 2018
Take home messages
- How residual herbicide products react with soil, water, temperature, light, organic matter and microbes determine their potential for plant-back risk.
- Drivers for pre-emergent residual herbicide breakdown are set by a product’s physical and chemical properties.
- Labels are legal documents that provide guidelines and key conditions that when met will prevent plant-back issues.
Discussion
Persistence of soil residual herbicides and their effect on plant-back crops are determined by a product’s physical and chemical properties and their interaction with the complex and highly variable environmental and biological systems in which they are used. This interaction can be simplified by looking at how these products interact on a basic level, then complexity can be added back into the system.
Where do we start? Herbicides are chemicals. When chemicals are applied to soil and plants in a particular environment, they interact. Just like a chemical reaction.
Product A + Product B + Conditions (Pressure/Heat) => Reaction => Product C
If we look at it through the eyes of an agronomist or grower:
Plant (G) x Environment (E) x Management (M) => Response => Yield
Agricultural chemicals and plants when used together produce a biological response leading to yield. Agronomists and growers need to make decisions based on their knowledge of how the desired crop will respond to the environment, the products and the management decisions implemented on the targeted paddock.
So what factors influence the persistence of residual chemicals? A wide range of factors shown in Figure 1 influence a product’s efficacy and residual persistence in a particular environment. By understanding a product’s physical and chemical properties and how they interact with their environment, an educated guess can be made on how a residual product will persist in our production systems.
Figure 1. Factors influencing the persistence of residual chemicals (Source: Richard Holzknecht 2018)
How do we manage plant-back risk? We need to understand what the risks are, and how long we are at risk. The risks that need to be managed with residual herbicides are crop safety, weed control performance and plant-back effects. These risks will vary for each residual herbicide product. Figure 2 highlights the difference between two residual products and how their concentration in the soil declines over time and their effect on risk.
Figure 2. Factors influencing the risks associated with using residual herbicide (Source: Richard Holzknecht and Roger Mandel 2015).
The tolerance of crops to a given product helps sets a maximum rate. The length of weed control provided by a residual product is determined by the product’s relationship between its effective use rate and the rate of product decline in the soil. Once the rate in the soil drops below that which provides sufficient weed control, a period of risk is entered where poor weed control and exposure to low rates increases potential weed resistance and crop damage to the following crop may occur. The length of this risk period varies by product and how it interacts with the environment in which it is used. Over time, the concentration of the product present in soil will decline until a point is reached at which it is safe to plant the next crop. This period of time will set a minimum plant-back period for a given environment. Unfortunately, the persistence of a residual herbicide is highly variable and driven by a wide range of environmental conditions. Therefore, more information is needed on what factors influence how long a residual product will persist in our production systems. The label for a given product provides a set of guidelines, e.g. plant-back periods and environmental conditions which need to be met to minimise plant-back effects.
What guidelines do labels provide to help us manage plant-back risk? A product label is a legal document that outlines the approved use patterns and conditions required to minimise any plant-back effects. They also highlight identified risks that can affect the product’s performance. Common label statements on crop use patterns, plant-back restrictions, incorporation timing, incorporation methods, planting methods, soil type, pH, surface conditions, organic matter, stubble, minimum rainfall amounts and rainfall distribution required before plant-back restrictions are met are identified on labels.
Why do some labels have more label guidelines for use than others? It all relates to a product’s physical and chemical properties (Table 1) and how it interacts in a wide range of environmental conditions. Additional understanding of a product’s physical and chemical properties can help identify what the likelihood for plant-back risk is for each product in any given season.
The primary methods for the residual herbicide breakdown are by microbial and hydrolysis. Both microbial and hydrolysis are driven by soil moisture. Hydrolysis breakdown is the chemical reaction of the product in the presence of water. Products with higher water solubility and lower soil binding are more available for hydrolysis and accessible for microbial breakdown. Microbial breakdown is reliant on the presence of the right soil microbe and soil conditions to enable breakdown. Soil conditions with low soil moisture, low organic matter, low soil pH and cold conditions will reduce the rates of microbial breakdown, increasing the risk of residual herbicide carryover to the next cropping season. Residual herbicides with shorter half-lives (DT50) require less time exposed to these soil conditions, and therefore, have shorter soil persistence.
Table 1. Physical and chemical properties for residual herbicides by herbicide group (Source: soil behaviour pre-emergent herbicides).
Product | Vapour pressure | Photo degradation | Water solubility mg/L | Soil binding Koc | Soil persistence Half life DT50 | Movement | Breakdown | Plant-back risk |
---|---|---|---|---|---|---|---|---|
Group B Sulfonylurea ALS inhibitors | ||||||||
Chlorsulfuron | 3.07 x 10-6 non-volatile | Negligible | 12500 high | 40 mobile | 36 (11-70) days moderately persistent | Very mobile, likely to move with soil water and off organic matter | Hydrolysis > in acidic soils, slow microbial, leaching | Dry conditions, alkaline soils |
Triasulfuron | 0.0021 non-volatile | Insignificant | 815 high | 60 mobile | 19 (3-48) days non-persistent | Very mobile, likely to move with soil water and off organic matter | Hydrolysis > neutral to acidic soil, slow microbial in alkaline soils | Dry conditions, alkaline soils |
Metsulfuron | 1.1 x 10-7 non-volatile | Negligible | 2790 high | 350 mobile | 10 (4-15) days non-persistent | Very mobile, likely to move with soil water and off organic matter | Hydrolysis > in acidic soils, slow microbial in alkaline soil, leaching | Dry conditions, alkaline soils |
Group B Imidazolinone ALS inhibitors | ||||||||
Imazapic | 0.01 non-volatile | Negligible | 2230 high | 145 moderately mobile | 232 (31-410) days persistent | Likely to move with soil water and off organic matter | Microbial, low microbial activity in acidic soils | Dry conditions, acid soils |
Imazapyr | 0.013 non-volatile | Negligible | 9740 high | 100 moderately mobile | 90 (25-142) days moderately persistent | Likely to move with soil water and off organic matter | Microbial, low microbial activity in acidic soils | Dry conditions, acid soils |
Imazethapyr | 1.3 x 10-2 non-volatile | Negligible | 1400 high | 52 mobile | 51 (24-142) days persistent | Likely to move with soil water and off organic matter | Microbial, low microbial activity in acidic soils | Dry conditions, acid soils |
Imazamox | 0.0133 non-volatile | Negligible | 626000 high | 62 mobile | 17 days non-persistent | Very mobile likely to move with soil water and off organic matter | Microbial, low microbial activity in acidic soils | Dry conditions, acid soils |
Product | Vapour pressure | Photo degradation | Water solubility mg/L | Soil binding Koc | Soil persistence Half life DT50 | Movement | Breakdown | Plant-back risk | |||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Group C Photosynthesis inhibitors | |||||||||||||||||||||||||
Diuron | 8.0 x 10-5 non-volatile | Limited, incorporation recommended | 35 low | 813 slightly mobile | 89 (20-231) days non persistent | Likely to bind with soil and organic matter | Hydrolysis variable, low microbial | Dry cool conditions, acidic soils | |||||||||||||||||
Simazine | 0.00081 non-volatile | Moderate, incorporation recommended | 4-7 low | 130 moderately mobile | 90 days moderately persistent | Likely to move with soil water and off organic matter | Low microbial, hydrolysis | Dry cool conditions, acidic soils | |||||||||||||||||
Atrazine | 0.0039 non-volatile | Moderate, incorporation recommended | 35 low | 100 moderately mobile | 60 (6-108) days moderately persistent | Likely to move with soil water and off organic matter | Microbial, hydrolysis | Dry cool conditions, acidic soils | |||||||||||||||||
Terbuthylazine | 0.12 non-volatile | Limited, incorporation recommended | 4-7 low | 170 moderately mobile | 22 (10-36) days non persistent | Likely to move with soil water and off organic matter | Hydrolysis in neutral to acid soils, slow microbial in alkaline soils | Dry cool conditions, acidic soils | |||||||||||||||||
Metribuzin | 0.121 non-volatile | Insignificant | 1165 high | 60 mobile | 14-28 days non-persistent | Very mobile, likely to move with soil water and off organic matter | Microbial | Dry cool conditions, acidic soils | |||||||||||||||||
Group D Microtubule inhibitors | |||||||||||||||||||||||||
Trifluralin | 9.5 volatile | Can be subject to degradation, incorporation required | <0.5 low | 15800 non mobile | 170 (35-375) days persistent | Likely to bind tightly to soil and organic matter | Volatility loss, photo degradation, slow microbial | Cool conditions | |||||||||||||||||
Pendimethalin | 1.92 volatile | Can be subject to degradation, incorporation required | <0.5 low | 17581 non mobile | 90 (24-186) days moderate persistent | Likely to bind tightly to soil and organic matter | Volatility loss, photo degradation, slow microbial | Cool conditions | |||||||||||||||||
Propyzamide | 0.03 non-volatile | Can be subject to degradation, incorporation required | 9 low | 840 slightly mobile | 56 (18-85) days moderately persistent | Likely to bind with soil and organic matter | Photo degradation, microbial | Cool conditions, acidic soils | |||||||||||||||||
Product | Vapour pressure | Photo degradation | Water solubility mg/L | Soil binding Koc | Soil persistence Half life DT50 | Movement | Breakdown | Plant-back risk | |||||||||||||||||
Group H Bleachers | |||||||||||||||||||||||||
Isoxaflutole | 1.0 x 10-3 non-volatile | Stable on surface, requires rainfall for activation | 4-7 low | 145 moderately mobile | 9-18 days non persistent | Likely to move with soil water and off organic matter | Hydrolysis, microbial | Dry cool conditions, acidic soils | |||||||||||||||||
Group I Growth Hormone inhibitors | |||||||||||||||||||||||||
Clopyralid | 1.36 volatile | Negligible | 143000 high | 5 very mobile | 40 (12-70) days moderately persistent | Very mobile likely to move with soil water and off organic matter | volatility loss leaching slow microbial | Dry cool conditions, acidic soils | |||||||||||||||||
Picloram | 8.0 x 10-5 non-volatile | Can be significant if applied to dry soil | 560 high | 13 very mobile | 90 (20-300) days moderate | Very mobile likely to move with soil water and off organic matter | Photo degradation, leaching, slow microbial | Dry cool conditions, acidic soils | |||||||||||||||||
Group J Lipid synthesis inhibitor | |||||||||||||||||||||||||
Triallate | 12 volatile | Negligible | 4.1 low | 3034 non-mobile | 46 (8-205) days moderate | Likely to move with soil water and off organic matter | Volatility, loss microbial | Dry cool conditions | |||||||||||||||||
Prosulfocarb | 0.79 non-volatile | Insignificant | 13.2 low | 1647 non-mobile | 10 (7-13) days non-persistent | Likely to bind tightly with soil and organic matter | Microbial | Dry cool conditions | |||||||||||||||||
Group K Very long chain fatty acid inhibitors | |||||||||||||||||||||||||
Pyroxasulfone | 2.4 x 10-3 non-volatile | Limited, incorporation recommended | 3.49 low | 223 moderately mobile | 22 (16-26) days non-persistent | Moderate movement with soil water and off organic matter | Microbial | Dry cool conditions | |||||||||||||||||
S-Metolachlor | 3.7 volatile | Can be significant, incorporation recommended | 480 Moderate | 200 moderately mobile | 21 (11-31) days non-persistent | Likely to move with soil water and off organic matter | Microbial | Dry cool conditions | |||||||||||||||||
Metazachlor | 0.09 non-volatile | Limited, incorporation recommended | 450 Moderate | 54 mobile | 8.6 days non-persistent | Likely to move with soil water and off organic matter | Microbial | Dry cool conditions | |||||||||||||||||
Conclusion
Understanding the plant-back risks associated with the use of residual herbicides is driven by the product used, and its interaction with the environment and production system in which it is used. Product labels are legal documents which guide the use of these products and seek to set ‘one size fits all’ recommendations to manage plant-back risks. However, a wider range of environmental factors and physical and chemical properties can impact on a product’s persistence in the soil. By understanding the effect these environmental factors have on a product, potential plant-back risks can be identified and a management decision to minimise the impact of these risks on our production systems prior to each season can be implemented.
Useful resources and references
Soil behaviour of pre-emergent herbicides
Acknowledgements
I would like to thank Mark Congreve and John Cameron for their work and report on GRDC Project ICN00016.
Contact details
Richard Holzknecht
Grains Research and Development Corporation
Grower Relations Manager - North
0408773865
Richard.holzknecht@grdc.com.au
@Richardholzkne
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