Labels and plant-backs - what you need to know for 2018

Take home messages

  • How residual herbicide products react with soil, water, temperature, light, organic matter and microbes determine their potential for plant-back risk.
  • Drivers for pre-emergent residual herbicide breakdown are set by a product’s physical and chemical properties.
  • Labels are legal documents that provide guidelines and key conditions that when met will prevent plant-back issues.

Discussion

Persistence of soil residual herbicides and their effect on plant-back crops are determined by a product’s physical and chemical properties and their interaction with the complex and highly variable environmental and biological systems in which they are used. This interaction can be simplified by looking at how these products interact on a basic level, then complexity can be added back into the system.

Where do we start? Herbicides are chemicals. When chemicals are applied to soil and plants in a particular environment, they interact. Just like a chemical reaction.

Product A + Product B + Conditions (Pressure/Heat) => Reaction => Product C

If we look at it through the eyes of an agronomist or grower:

Plant (G) x Environment (E) x Management (M) => Response => Yield

Agricultural chemicals and plants when used together produce a biological response leading to yield. Agronomists and growers need to make decisions based on their knowledge of how the desired crop will respond to the environment, the products and the management decisions implemented on the targeted paddock.

So what factors influence the persistence of residual chemicals? A wide range of factors shown in Figure 1 influence a product’s efficacy and residual persistence in a particular environment. By understanding a product’s physical and chemical properties and how they interact with their environment, an educated guess can be made on how a residual product will persist in our production systems.

Figure 1. Factors influencing the persistence of residual chemicals (Source: Richard Holzknecht 2018)

How do we manage plant-back risk? We need to understand what the risks are, and how long we are at risk. The risks that need to be managed with residual herbicides are crop safety, weed control performance and plant-back effects. These risks will vary for each residual herbicide product. Figure 2 highlights the difference between two residual products and how their concentration in the soil declines over time and their effect on risk.

Figure 2. Factors influencing the risks associated with using residual herbicide (Source: Richard Holzknecht and Roger Mandel 2015).

The tolerance of crops to a given product helps sets a maximum rate. The length of weed control provided by a residual product is determined by the product’s relationship between its effective use rate and the rate of product decline in the soil. Once the rate in the soil drops below that which provides sufficient weed control, a period of risk is entered where poor weed control and exposure to low rates increases potential weed resistance and crop damage to the following crop may occur. The length of this risk period varies by product and how it interacts with the environment in which it is used. Over time, the concentration of the product present in soil will decline until a point is reached at which it is safe to plant the next crop. This period of time will set a minimum plant-back period for a given environment. Unfortunately, the persistence of a residual herbicide is highly variable and driven by a wide range of environmental conditions. Therefore, more information is needed on what factors influence how long a residual product will persist in our production systems. The label for a given product provides a set of guidelines, e.g. plant-back periods and environmental conditions which need to be met to minimise plant-back effects.

What guidelines do labels provide to help us manage plant-back risk? A product label is a legal document that outlines the approved use patterns and conditions required to minimise any plant-back effects. They also highlight identified risks that can affect the product’s performance. Common label statements on crop use patterns, plant-back restrictions, incorporation timing, incorporation methods, planting methods, soil type, pH, surface conditions, organic matter, stubble, minimum rainfall amounts and rainfall distribution required before plant-back restrictions are met are identified on labels.

Why do some labels have more label guidelines for use than others? It all relates to a product’s physical and chemical properties (Table 1) and how it interacts in a wide range of environmental conditions. Additional understanding of a product’s physical and chemical properties can help identify what the likelihood for plant-back risk is for each product in any given season.

The primary methods for the residual herbicide breakdown are by microbial and hydrolysis. Both microbial and hydrolysis are driven by soil moisture. Hydrolysis breakdown is the chemical reaction of the product in the presence of water. Products with higher water solubility and lower soil binding are more available for hydrolysis and accessible for microbial breakdown. Microbial breakdown is reliant on the presence of the right soil microbe and soil conditions to enable breakdown. Soil conditions with low soil moisture, low organic matter, low soil pH and cold conditions will reduce the rates of microbial breakdown, increasing the risk of residual herbicide carryover to the next cropping season. Residual herbicides with shorter half-lives (DT50) require less time exposed to these soil conditions, and therefore, have shorter soil persistence.

Table 1. Physical and chemical properties for residual herbicides by herbicide group (Source: soil behaviour pre-emergent herbicides).

Product

Vapour pressure

Photo degradation

Water solubility mg/L

Soil binding Koc

Soil persistence Half life

DT50

Movement

Breakdown

Plant-back risk

Group B Sulfonylurea ALS inhibitors

Chlorsulfuron

3.07 x 10-6

non-volatile

Negligible

12500

high

40

mobile

36 (11-70) days moderately persistent

Very mobile, likely to move with soil water and off organic matter

Hydrolysis > in acidic soils,

slow microbial, leaching

Dry conditions, alkaline soils

Triasulfuron

0.0021

non-volatile

Insignificant

815

high

60

mobile

19 (3-48) days non-persistent

Very mobile, likely to move with soil water and off organic matter

Hydrolysis > neutral to acidic soil, slow microbial in alkaline soils

Dry conditions, alkaline soils

Metsulfuron

1.1 x 10-7

non-volatile

Negligible

2790

high

350

mobile

10 (4-15) days non-persistent

Very mobile, likely to move with soil water and off organic matter

Hydrolysis > in acidic soils,

slow microbial in alkaline soil, leaching

Dry conditions, alkaline soils

Group B Imidazolinone ALS inhibitors

Imazapic

0.01

non-volatile

Negligible

2230

high

145

moderately mobile

232 (31-410) days persistent

Likely to move with soil water and off organic matter

Microbial, low microbial

activity in acidic soils

Dry conditions,

acid soils

Imazapyr

0.013

non-volatile

Negligible

9740

high

100

moderately mobile

90 (25-142) days moderately persistent

Likely to move with soil water and off organic matter

Microbial, low microbial

activity in acidic soils

Dry conditions,

acid soils

Imazethapyr

1.3 x 10-2

non-volatile

Negligible

1400

high

52

mobile

51 (24-142) days persistent

Likely to move with soil water and off organic matter

Microbial, low microbial

activity in acidic soils

Dry conditions,

acid soils

Imazamox

0.0133

non-volatile

Negligible

626000

high

62

mobile

17 days

non-persistent

Very mobile likely to move with soil water and off organic matter

Microbial, low microbial

activity in acidic soils

Dry conditions,

acid soils

Product

Vapour pressure

Photo degradation

Water solubility mg/L

Soil binding Koc

Soil persistence Half life

DT50

Movement

Breakdown

Plant-back risk

Group C Photosynthesis inhibitors

Diuron

8.0 x 10-5

non-volatile

Limited, incorporation recommended

35

low

813

slightly mobile

89 (20-231) days non persistent

Likely to bind with soil and organic matter

Hydrolysis variable,

low microbial

Dry cool conditions,

acidic soils

Simazine

0.00081

non-volatile

Moderate, incorporation recommended

4-7

low

130

moderately mobile

90 days moderately persistent

Likely to move with soil water and off organic matter

Low microbial,

hydrolysis

Dry cool conditions,

acidic soils

Atrazine

0.0039

non-volatile

Moderate, incorporation recommended

35

low

100

moderately mobile

60 (6-108) days moderately persistent

Likely to move with soil water and off organic matter

Microbial,

hydrolysis

Dry cool conditions,

acidic soils

Terbuthylazine

0.12

non-volatile

Limited, incorporation recommended

4-7

low

170

moderately mobile

22 (10-36) days non persistent

Likely to move with soil water and off organic matter

Hydrolysis in neutral to

acid soils, slow microbial

in alkaline soils

Dry cool conditions,

acidic soils

Metribuzin

0.121

non-volatile

Insignificant

1165

high

60

mobile

14-28 days

non-persistent

Very mobile, likely to move with soil water and off organic matter

Microbial

Dry cool conditions,

acidic soils

Group D Microtubule inhibitors

Trifluralin

9.5

volatile

Can be subject to degradation, incorporation required

<0.5

low

15800 non mobile

170 (35-375) days persistent

Likely to bind tightly to soil and organic matter

Volatility loss,

photo degradation,

slow microbial

Cool conditions

Pendimethalin

1.92

volatile

Can be subject to degradation, incorporation required

<0.5

low

17581 non mobile

90 (24-186) days moderate persistent

Likely to bind tightly to soil and organic matter

Volatility loss,

photo degradation,

slow microbial

Cool conditions

Propyzamide

0.03

non-volatile

Can be subject to degradation, incorporation required

9

low

840 slightly mobile

56 (18-85) days moderately persistent

Likely to bind with soil and organic matter

Photo degradation,

microbial

Cool conditions, acidic soils

Product

Vapour pressure

Photo degradation

Water solubility

mg/L

Soil binding Koc

Soil persistence

Half life

DT50

Movement

Breakdown

Plant-back risk

Group H Bleachers

Isoxaflutole

1.0 x 10-3

non-volatile

Stable on surface, requires rainfall for activation

4-7

low

145

moderately mobile

9-18 days

non persistent

Likely to move with soil water and off organic matter

Hydrolysis,

microbial

Dry cool conditions,

acidic soils

Group I Growth Hormone inhibitors

Clopyralid

1.36

volatile

Negligible

143000

high

5

very mobile

40 (12-70) days moderately persistent

Very mobile likely to move with soil water and off organic matter

volatility loss leaching slow microbial

Dry cool conditions,

acidic soils

Picloram

8.0 x 10-5

non-volatile

Can be significant if applied to dry soil

560

high

13

very mobile

90 (20-300) days moderate

Very mobile likely to move with soil water and off organic matter

Photo degradation, leaching,

slow microbial

Dry cool conditions,

acidic soils

Group J Lipid synthesis inhibitor

Triallate

12

volatile

Negligible

4.1

low

3034

non-mobile

46 (8-205) days moderate

Likely to move with soil water and off organic matter

Volatility,

loss microbial

Dry cool

conditions

Prosulfocarb

0.79

non-volatile

Insignificant

13.2

low

1647

non-mobile

10 (7-13) days non-persistent

Likely to bind tightly with soil and organic matter

Microbial

Dry cool conditions

Group K Very long chain fatty acid inhibitors

Pyroxasulfone

2.4 x 10-3 non-volatile

Limited, incorporation recommended

3.49

low

223

moderately mobile

22 (16-26) days non-persistent

Moderate movement with soil water and off organic matter

Microbial

Dry cool conditions

S-Metolachlor

3.7

volatile

Can be significant, incorporation recommended

480

Moderate

200

moderately mobile

21 (11-31) days non-persistent

Likely to move with soil water and off organic matter

Microbial

Dry cool conditions

Metazachlor

0.09

non-volatile

Limited, incorporation recommended

450 Moderate

54

mobile

8.6 days

non-persistent

Likely to move with soil water and off organic matter

Microbial

Dry cool conditions

                          

Conclusion

Understanding the plant-back risks associated with the use of residual herbicides is driven by the product used, and its interaction with the environment and production system in which it is used. Product labels are legal documents which guide the use of these products and seek to set ‘one size fits all’ recommendations to manage plant-back risks. However, a wider range of environmental factors and physical and chemical properties can impact on a product’s persistence in the soil. By understanding the effect these environmental factors have on a product, potential plant-back risks can be identified and a management decision to minimise the impact of these risks on our production systems prior to each season can be implemented.

Useful resources and references

Soil behaviour of pre-emergent herbicides

Acknowledgements

I would like to thank Mark Congreve and John Cameron for their work and report on GRDC Project ICN00016.

Contact details

Richard Holzknecht
Grains Research and Development Corporation
Grower Relations Manager - North
0408773865
Richard.holzknecht@grdc.com.au
@Richardholzkne